Addition of Strong
Brønsted Acids, Regioselectivity and the
Markovnikov Rule,.
Rearrangement of Carbocations,.
Addition of Lewis Acids
(Electrophilic Reagents) Stereoselectivity in
Addition Reactions to Double Bonds,
Brønsted Acid Additions, Addition Reactions
Initiated by Electrophilic Halogen.
2-
Alcohols
Diols
and triols , Alcohol Nomenclature,
Physical
properties,
Hydrolysis of alkyl halides, Reaction of
Grignard reagents with aldehydes and ketones,
Reaction of organolithium reagents with
aldehydes and ketones, Reaction of Grignard
reagents with esters, Acid catalyzed hydration
of alkenes, Oxymercuration-demercuration of
alkenes, Hydroboration oxidation of alkenes,
Reaction of an amine with nitrous acid,
Reduction of compounds by NaBH4 and
LiAlH4
(Synthesis of alcohol), From epoxides,
Chemical properties of alcohol
,
Electrophilic Substitution at Oxygen
,
Acidic nature of alcohol, Reaction with Thionyl
chloride and phosphorus Halides Reaction of
alcohol with Hydrogen Halides, Haloform test
only for 2–alkanone , Dehydration of alcohols,
Alcoholation of alkyne, Acylation of alcohol,
Dehydration of alcohols, Alcoholation of alkyne,
Reaction with CH2N2 or CH2CO,
Esterification, Methods of distinguishing
between primary, secondary and tertiary
alcohols,
Phenols,
Reactions of Phenols.
3-
Alkyl Halide Reactions
Introduction,NOMENCLATURE,Physical
properties,Physical properties,Reaction of Alkyl
Halides,Reactions at
sp³-hybridized
Carbons,Substitution
and Elimination, Nucleophilicity, Solvent
Effects, The Alkyl Moiety, Molecularity,
Kinetics, Reactions
of Alkyl Halides with Reducing Metals , Reactions
of Dihalides, Preparation
of Alkynes by Dehydrohalogenation, Elimination
Reactions,SN1
mechanism,E2
Reaction, E1 Reaction .
4-
Aldehydes and Ketones
Background Information for Aldehydes and
Ketones,Structure ,Shape ,Properties , andUses
Nomenclature of Aldehydes and Ketones,IUPAC ,
andCommon .Synthesis of Aldehydes and
Ketones,Oxidation of Alcohols ,Friedel-Craft
Acylation of Benzene Ozonolysis of Alkenes ,and
From Acid Halides .Reactions of Aldehydes and
Ketones.Reaction with Organometallics .Reduction
to Alcohols .Reduction to Alkanes .Formation of
Imine Derivatives .Oxidation of Aldehydes to
Carboxylic Acids.
5-
Carboxylic Acids
Nomenclature,Physical
Properties(Structure,Acidity,Reactivity),Reactions
of Carboxylic Acids[(
Preparation of Acid Anhydrides,of Carboxylic
Acid Derivatives,Nucleophilic
Acyl Substitution ,Preparation
of Acyl Chlorides,Preparation of
Amides)],Reduction of Carboxylic Acids,a-Halogenation(Hell-Volhard-Zelinsky reaction)
,Decarboxylation,Spectroscopic
Analysis.
6-
Carboxylic Acids Drivatives
Nomenclature of Carboxylic Acid Derivatives
,Acyl
Halides or Acid Halides,Acid
Anhydrides,
Amides,Nitriles,Structure
of Carboxylic Acid Derivatives,Overview of
Nucleophilic Acyl Substitution,Reactions of
Carboxylic Acid Derivatives,Interconversion
Reactions of Acid Anhydrides,Interconversion
Reactions of Esters,Interconversion Reactions of
Amides,Reactions of Nitriles,Friedel-Crafts
Acylation of Benzene,Hydrolysis
of Esters,Preparation
of Esters,Reduction
of Esters,Reactions of RLi and RMgX with Esters
,Hydrolysis
of Amides,Reduction of Amides,Hydrolysis of
Nitriles,Reduction of Nitriles,Spectroscopic
Analysis.
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